Reductive Catalytic Fractionation of Wheat Straw Biomass
نویسندگان
چکیده
The reductive catalytic fractionation (RCF) is a promising method for the development of “lignin-first” biorefineries. Apart from widely investigated virgin woody biomass, it essential to explore potential waste biomass feedstocks. Herein, RCF wheat straw examined produce lignin mono-/oligomers along with processable carbohydrate pulp. use different catalysts (Ru/C and Ru/Al2O3) catalyst loadings (0–20% w/wbiomass) revealed superior performance Ru/C, which resulted in largest yield phenolic monomers (up ∼25 wt % initial acid-insoluble lignin) lowest formation high-molecular-weight fragments extracted oil. Furthermore, operating temperature was shown substantially affect both extraction–depolymerization polysaccharides preservation–processability. For reaction time 3 h, an increase 200 250 °C >2-fold boost yields oil monophenolics, while recovery decreased by about 30 (with ∼20% lower enzymatic digestibility). An economic assessment highlighted that high-temperature treatment becomes most profitable configuration as market price products increases. Overall, this work provides insight into adoption upgrading lignocellulose inexpensive available biomass.
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ژورنال
عنوان ژورنال: ACS Sustainable Chemistry & Engineering
سال: 2022
ISSN: ['2168-0485']
DOI: https://doi.org/10.1021/acssuschemeng.2c02012